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Feb 28, 2024

YCN Newsletter 20 - Research in Spot by Emilija Nidžović

Synthesis, processing and characterization of high-entropy spinel oxides

Spinel oxides are metal oxides with the general formula AB2O4 and the spinel structure, where A and B represent different cations located at tetrahedral (A) and octahedral (B) sites. High-entropy spinel oxides (HESOs) contain five or more cations in these positions and have a single-phase crystal structure. These oxides have specific characteristics which make them suitable for a multitude of technological applications (e.g., catalysts, adsorbents, photocatalysts, sensors). Since the pioneering work of Dąbrowa and associates in 2018, various researchers have worked on the synthesis of HESOs, using different precursors and methods, as well as on investigating their properties.

My research focuses on synthesizing HESOs by utilizing the self-propagating room temperature (SPRT) method, which has not been used for this purpose in previous research. The main advantages of this approach are its time- and cost-effectiveness. Using it, I was able to synthesize single-phased high entropy spinel oxides of different compositions. After the synthesis, which produces samples in powder form, spark plasma sintering (SPS) is utilized in order to achieve densification. The sintering process occurs very fast and results in high-density ceramics.

Further steps of my PhD research will include assessing the structural, mechanical, thermal, electrical, magnetic, and other properties of the synthesized and processed samples. The ultimate goal is to contribute to both theoretical understanding and practical application of these materials.

Emilija Nidžović

Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of thе Republic of Serbia, University of Belgrade, Belgrade, Serbia

emilija.nidzovic@vin.bg.ac.rs

Latest news

2025 ECerS International Ceramist Student Exchange Program – 3rd call!

In the frame of the 2025 ECerS International Student exchange program, ECerS is opening a first call to allow grants to European Students to attend the 2025 International Symposium on Green Processing for Advanced Ceramics (IGPAC 2025), organised by the Ceramic Society of Japan, from 5th to 9th October 2025 in Ise-Shima/Mie, Japan.

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Next Deadline to apply to the JECS Trust for Mobility projects is 31st August 2025!

Please note that the decisions of the JECS Trust board will not be known before end of October 2025. Activities submitted for the deadline of 31st August 2025 for support from the JECS Trust should then not begin before November 2025.

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